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A novel Zn phthalocyanine bearing 4 salicylideniminophenyloxy  substituents on peripheral positions was synthesized from the reaction  of 4-aminophenoxy substituted phthalocyanine and salicylaldehyde.  The  condensation reaction of salicylidene Schiff base groups and  benzeneboronic acid produced a new phthalocyanine carrying  benzeneboronic acid ester derivatives as substituents.  Ethoxy groups  were bound to boronic acid as a second ligand.  The presence of B-N  bond interactions enhanced the stability of this boronated  phthalocyanine derivative, which exhibited sufficient air stability  during the purification and characterization processes.  The novel  compounds were characterized by using elemental analysis, IR, 1H-NMR,  11B-NMR, 13C-NMR, UV-Vis and MALDI-TOF MS spectral data.

A novel soluble phthalocyanine capable of binding four boronic esters