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Ferroelectric polymers are particularly attractive for applications in flexible electronic devices, and controlling its crystalline phase growth is crucial for obtaining optimized ferroelectric properties. Herein we report that a very low introduction (0.2% (w)) of single-domain ferroelectric PbTiO3 nanoplates can effectively mediate the nucleation and subsequent growth of a crystalline phase within P(VDF-TrFE) (denoted by PVTF), forming highly oriented films and significantly improving the ferroelectric properties due to an alignment of the polarization directions of the polymer and the nanoplates.

Perovskite Ferroelectric Nanoplates Induced a Highly Oriented Growth of P (VDF-TrFE) Films