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The phase behaviors of 1-butyl-3-methylimidazolium hexafluorophosphate([bmim] [PF6]) + water+methanol,[bmim][PF6]+water+ethanol,[bmim][PF6]+water+2-propanol,and [bmim][PF6]+water+1propanol ternary systems were determined at 298.15 K and ambient pressure.It was demonstrated that when the mole fractions of the alcohols in the water + alcohol solutions were 0.55-1.00,0.40-0.75,and 0.35-0.50 for methanol,ethanol,and 2-propanol,respectively,the [bmim][PF6] was totally dissolved in the aqueous alcohol solutions due to a strong co-solvent effect.However,water+1-propanol did not exhibit this kind of behavior.Both the size and structure of the alcohols significantly affected the phase behaviors of the ternary systems.

Phase Behaviors of 1-Butyl-3-methylimidazolium Hexafluorophosphate+Water+Alcohol Systems