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Katsumadain A, a naturally occurring inuenza virus neuraminidase (NA) inhibitor, was synthesized by using a bioinspired, organocatalytic enantioselective 1,4-conjugate addition of styryl-2-pyranone with cinnamaldehyde, followed by a tandem Horner-Wadsworth-Emmons/oxa Michael addition.

Bioinspired total synthesis of katsumadain A by organocatalytic enantioselective 1,4-conjugate addition