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The enzymatically catalyzed synthesis of a copolymer of 4-tert-butylphenol and 4-ferrocenylphenol by horse radish peroxidase (HRP) in the presence of H(2)O(2) in a 1,4-dioxane/water system is described. Furthermore, polymer-analogous alkylation of the free hydroxy groups and subsequent click reaction with mono-6-azido-6-desoxy-β-cyclodextrin (N(3)-β-CD) was carried out. The formation of inter- and intramolecular inclusion complexes was investigated by DLS measurement.

beilstein journal of organic chemistry

New enzymatically polymerized copolymers from 4-<i>tert</i>-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin

New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin