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Anthracene-based adenines  1  and  2  have been designed and synthesized, and their metal ion recognition properties have been established fluorometrically. Both molecules exhibit Cu 2+  induced ON-OFF type signaling patterns over the other representative metal ions studied. Compound  1  exhibits 97% quenching of emission in the presence of Cu 2+  whilst derivative  2  shows 81% quenching under similar experimental conditions.

Anthracene coupled adenine for the selective sensing of copper ions