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Three novel phenyltelluroalkoxyl functionalized tweezer-like calix[4]arenes  6 – 8  and two monophenyltelluropropoxyl functionalized calix[4]arenes  10  (cone conformer) and  12  (partial cone conformer) were synthesized and characterized. They are good Ag + -selective ionophores in ion-selective electrodes evaluated by electromotive force measurements of polymer membrane electrodes. The tweezer-like ionophores  6 – 8  showed excellent extraction ability towards Ag +  and Hg 2+ .

Synthesis and properties of calix[4]arene telluropodant ethers as Ag+ selective sensors and Ag+, Hg2+ extractants

Synthesis and properties of calix[4]arene telluropodant ethers as Ag⁺ selective sensors and Ag⁺, Hg²⁺ extractants