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A chiral phenol–NHC ligand enabled the copper-catalyzed enantioselective conjugate reduction of α,β-unsaturated esters. The phenol moiety of the chiral NHC ligand played a critical role in producing the enantiomerically enriched products. The catalyst worked well for various ( Z )-isomer substrates. Opposite enantiomers were obtained from ( Z )- and ( E )-isomers, with a higher enantiomeric excess from the ( Z )-isomer.

Copper-catalyzed enantioselective conjugate reduction of α,β-unsaturated esters with chiral phenol–carbene ligands