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Four new Grubbs-type precatalysts [RuCl(H 2 IMes)(O^N)(=CHPh)], where [O^N = α,α-diphenyl-(3-methylpyridin-2-yl)methanolato, α,α-diphenyl-(4-methylpyridin-2-yl)methanolato, α,α-diphenyl-(5-methylpyridin-2-yl)methanolato and α,α-diphenyl-(3-methoxypyridin-2-yl)methanolato] were synthesized and tested for their activity, stability and selectivity in the 1-octene metathesis reaction. Overall the precatalysts showed good activity and high stability for the metathesis of 1-octene at temperatures above 80 °C and up to 110 °C. Selectivities towards the primary metathesis products, i.e., 7-tetradecene and ethene, above 85% were obtained with all the precatalysts at 80 and 90 °C. High selectivities were also observed at 100 °C for the 4-Me- and 3-OMe-substituted precatalysts. With an increase in temperature an increase in isomerisation products and secondary metathesis products were observed with the latter reaching values &gt;20% for the 3-OMe- and 3-Me-substituted precatalysts at 110 and 100 °C, respectively. All the precatalysts exhibits first-order kinetics at 80 °C with the 3-substituted precatalysts the slowest. The behaviour of the 3-substituted precatalysts can be attributed to electronic and steric effects associated with the adjacent bulky phenyl groups.

beilstein journal of organic chemistry

Catalysis of linear alkene metathesis by Grubbs-type ruthenium alkylidene complexes containing hemilabile α,α-diphenyl-(monosubstituted-pyridin-2-yl)methanolato ligands