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The asymmetric cycloaddition of TIPS nitronate catalyzed by "Cu(II)-bisoxazoline" gave the 2-isoxazoline product in 95% yield, which was converted into tert -butyl (3 S ,5 R )-6-hydroxy-3,5- O -isopropylidene-3,5-dihydroxyhexanoate in 14 steps through a β-hydroxy ketone.

Application of chiral 2-isoxazoline for the synthesis of syn-1,3-diol analogs