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Stereoretentive olefin metathesis based on ruthenium dithiolate complexes has become a very active field of research within the past years. This unique catalyst class is able to kinetically produce both Z - and E -alkenes in high stereochemical purity (typically &gt;95:5) starting from stereochemically pure Z - or E -alkenes. The aim of this tutorial review is to organize the reported information concerning ruthenium dithiolate catalysts in a logic manner, thus providing an "operators handbook" for chemists who wish to apply this methodology in synthesis.

A tutorial review of stereoretentive olefin metathesis based on ruthenium dithiolate catalysts