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Cobalamins (B 12 ) play various important roles in vivo. Most B 12 -dependent enzymes are divided into three main subfamilies: adenosylcobalamin-dependent isomerases, methylcobalamin-dependent methyltransferases, and dehalogenases. Mimicking these B 12 enzyme functions under non-enzymatic conditions offers good understanding of their elaborate reaction mechanisms. Furthermore, bio-inspiration offers a new approach to catalytic design for green and eco-friendly molecular transformations. As part of a study based on vitamin B 12 derivatives including heptamethyl cobyrinate perchlorate, we describe biomimetic and bioinspired catalytic reactions with B 12 enzyme functions. The reactions are classified according to the corresponding three B 12 enzyme subfamilies, with a focus on our recent development on electrochemical and photochemical catalytic systems. Other important reactions are also described, with a focus on radical-involved reactions in terms of organic synthesis.

Learning from B12 enzymes: biomimetic and bioinspired catalysts for eco-friendly organic synthesis

Learning from B₁₂ enzymes: biomimetic and bioinspired catalysts for eco-friendly organic synthesis