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A highly efficient, simple and environmentally friendly synthesis of 3-arylquinolines has been developed in the presence of Al 2 O 3 /MeSO 3 H via one-pot reaction of anilines and styrene oxide. This methodology provides very rapid access to 3-arylquinolines in good to excellent yields under solvent-free conditions at room temperature in air.

beilstein journal of organic chemistry

Solvent-free and room temperature synthesis of 3-arylquinolines from different anilines and styrene oxide in the presence of Al2O3/MeSO3H