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)Abstract The effect of silver nanoparticles (NPs) incorporation on the electronic properties of poly (3, 4-ethylenedioxythiphene) : poly(styrenesulfonate) (PEDOT : PSS) films was investigated. The surface of silverNPs was stabilized with trisodium citrate to control the size of silver NPs and prevent their aggregation. Weobtained ca. 5 nm sized silver NPs and dispersed NPs in PEDOT : PSS solution. Sheet resistance, surfacemorphology, bonding state, and work function values of the PEDOT : PSS films were modified by silver NPsincorporation as well as annealing temperature. Sodium in silver NPs solution could lead to a decrease of workfunction of PEDOT : PSS; however, large content of silver NPs have an effect on the increase in work function,resulting from charge localization on the silver NPs and a decrease in the number of charge-trapping-relateddefects by chemical bond formation.Key wordsPEDOT : PSS; silver; nanoparticle; work function; charge localization.

han'gug jaeryo haghoeji/han-guk jaeryo hakoeji

Effect of Annealing Temperature with Silver NanoparticlesIncorporation on the Electronic Structure ofPoly (3, 4-ethylenedioxythiphene):poly (styrenesulfonate) Film