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Four new [copper(II) and iron(III)] complexes were synthesized using N-(4-hydroxy-3((piperidin-1-yl)methyl)phenyl)acetamide (HL) a Mannich base as ligand. All compounds were successfully characterized by elemental analysis, conductivity measurements, Ultraviolet-visible, Infrared, and Nuclear Magnetic Resonance spectroscopy. Furthermore, the structural determination of HL by X-ray diffraction technique at room temperature showed that the ligand crystallized in the monoclinic crystal system with space group Cc and Z=4. Structural analysis revealed the chelation of the ligand and the bonding mode of the thiocyanate group. All the metal complexes demonstrated considerable abilities to oxidize 3, 5-di-tert-butylcatechol in DMF under aerobic conditions. Complex 3 (with an iron(III) center) displayed the highest turnover rate of 14.69 ± 0.71 h.

revista de chimie

Impact of Thiocyanate on Catalytic Abilities of Metal Complexes of 4-N-(4-hydroxy-3-((piperidin-1-yl)methyl) phenyl)acetamide (HL). X-ray Crystal Structure of HL