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Batch kinetic experiments were conducted to investigate the feasibility of using carboxylmethyl cellulose (CMC)-stabilized nano zero valent iron (nZVI) particles for immobilization of Cu in water. The effects of nZVI concentration, pH, and initial concentration of Cu have been studied. Cu immobilization increased from 59.10% to 98.10% as the nZVI concentration increased from 0.2 to 2.0 g/l. The adsorption kinetics of Cu ions was fitted to a pseudo-second order model and both Langmuir and Freundlich isotherms fit experimental data. SEM–EDX indicates that slightly porous and fragile particles were formed due to the corrosion on the nZVI surface.

Immobilization of Cu2+ using stabilized nano zero valent iron particles in contaminated aqueous solutions