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...25 Referat  33 Introduction  39 Objectives  59 Chapter 1. Heterogeneous Zinc glutarate catalyst study in copolymerization reactions among propylene oxide and carbon dioxide in batch and subcritical conditions  65 Chapter 2. Effect of Zn/Co initial preparation ratio in the activity of a Double Metal Cyanide catalyst for propylene oxide and carbon dioxide copolymerization  139 Chapter 3. Doble Metal Cyanide catalyst and propylene oxide influence on the activation stage study and copolymerization reaction  173 Conclusions  203 Resumen  209 Future work  239 Appendix I. Solubility of CO2 in different polypropylene carbonates  245 Acknowledgements  259 About the author  265

Heterogeneous catalytic copolymerization reactions of carbon dioxide and propylene oxide over polyalcohols under subcritical conditions