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Synthesis of Dihydrofurans through Lewis Base Catalyzed One Pot Cascade Condensation Tao Liao A one-pot synthesis of substituted dihydrofurans was developed from a Lewis base catalyzed three-component cascade condensation with nitroalkenes, aldehydes and 1,3-dicarbonyl compounds. A large substrate scopes were prepared with excellent diastereoselectivity (trans product only) and excellent yield (up to 95%). Synthesis of Chiral Triazole Derivatives through Mitsunobu Reaction Tao Liao Large substrate scope of chiral triazole derivatives were prepared through Mitsunobu reaction, this reaction gave excellent yields and complete stereochemistry inversion, making this strategy one practical approach for the synthesis of enantiomeric enriched triazole analogous. Interesting N-2 selectivity was observed even with the well know N-1 preferred benzotriazole, which may reveal an alternative strategy for the challenging N-2 functionalization.

Development of Substituted Dihydrofurans and 1,2,3-NH-Triazoles through Lewis Base Catalyzed Cascade Condensation and Their Application in Synthesis of Chiral Triazole Derivatives through Mitsunobu Reaction