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Estimating post mining water quality at surface mines is complex, and influenced by the hydrochemical evolution of the mine spoil. Agglomerative hierarchical clustering was used to group hydrochemistry of the DLM X bench sampled in 1994, 1999, 2010 and 2012. Results were mapped to demonstrate spatial variations in response to reclamation attempts over time. Spatial patterns were discerned over multiple sampling periods and indicated that aquifer chemistry has continued to evolve over this period. The results show that induced alkaline recharge temporarily neutralized acidity and can have lasting effects on groundwater chemistry in mine spoil. 2.

Quantification of acid loads and delineation of hydrochemical facies at a phreatic mine spoil aquifer