English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

This work is focused on the removal of cobalt from aqueous solutions using the greenhouse crop residue and biochars resulting from its pyrolysis at different temperatures, which have not been previously used for this purpose. This study aims to provide insights into the effect of pyrolysis temperature as a key parameter on the cobalt adsorption capacity of these materials. Firstly, the main physicochemical properties of greenhouse crop residue and its biochars prepared under different pyrolysis temperatures were characterized by elemental analysis and FT-IR, among others. Then, the cobalt adsorption capacity of materials was evaluated in batch systems. The best results were obtained for the biochar prepared by pyrolysis at 450 °C (adsorption capacity of 28 mg/g). Generally, the adsorption capacity of the materials increased with pyrolysis temperature. However, when the treatment temperature was increased up to 550 °C, a biochar with worse properties and behavior than cobalt adsorbent was produced. Rather than surface area and other physical properties, functional groups were found to influence cobalt adsorption onto the prepared materials. The adsorption kinetics showed that the adsorption followed pseudo-second-order kinetics model. The obtained equilibrium data were fitted better by the Langmuir model rather than the Freundlich model. Finally, decomposition of loaded-materials was analyzed to assess their possible recycling as fuel materials. The study suggested that greenhouse crop residue can be used as a low-cost alternative adsorbent for cobalt removal from aqueous solutions.

Greenhouse Crop Residue and Its Derived Biochar: Potential as Adsorbent of Cobalt from Aqueous Solutions