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Two-dimensional (2D) crystalline structures based on a honeycomb geometry are analyzed by computer simulations using the Monte Carlo method in the isobaric-isothermal ensemble. The considered crystals are formed by hard discs (HD) of two different diameters which are very close to each other. In contrast to equidiameter HD, which crystallize into a homogeneous solid which is elastically isotropic due to its six-fold symmetry axis, the systems studied in this work contain artificial patterns and can be either isotropic or anisotropic. It turns out that the symmetry of the patterns obtained by the appropriate arrangement of two types of discs strongly influences their elastic properties. The Poisson’s ratio (PR) of each of the considered structures was studied in two aspects: (a) its dependence on the external isotropic pressure and (b) in the function of the direction angle, in which the deformation of the system takes place, since some of the structures are anisotropic. In order to accomplish the latter, the general analytic formula for the orientational dependence of PR in 2D systems was used. The PR analysis at extremely high pressures has shown that for the vast majority of the considered structures it is approximately direction independent (isotropic) and tends to the upper limit for isotropic 2D systems, which is equal to +1. This is in contrast to systems of equidiameter discs for which it tends to 0.13, i.e., a value almost eight times smaller.

Extreme Poisson’s Ratios of Honeycomb, Re-Entrant, and Zig-Zag Crystals of Binary Hard Discs