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The psychological health and work commitment of miners are prerequisites to ensuring their sustainable safety behavior, and it is also significant to the sustainable development of coal mines in China. In this context, we conducted a questionnaire survey among coal miners of state-owned coal enterprises to explore the relationships between cultural emotion, unemployment risk perception, Big Five personality traits, and work commitment. The results reveal that (1) cultural emotion and its three dimensions played a significant positive role in promoting work commitment. (2) Unemployment risk perception, policy unemployment risk perception, and individual differential unemployment risk perception had a negative moderating effect. (3) Moreover, work commitment was associated with differences in personality characteristics except for agreeableness. This research is of important theoretical value and practical significance, as it can guide Chinese coal miners to increase their work commitment and thereby improve safety in production.

A Comprehensive Model of the Relationship between Miners’ Work Commitment, Cultural Emotion and Unemployment Risk Perception