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A non-invasive real-time detection technique for phthalates in Chinese liquor is proposed in this paper. This method is based on the measurement of Faradaic impedance in the presence of a redox probe, [Fe(CN) 6 ] 3-/4- , upon the absorption of phthalates to the graphene electrode surface. This absorption activity is according to the π-π stacking interactions between phthalates and the graphene working electrode which allows direct sampling and analyte preconcentration. The absorption of phthalates retards the interfacial electron-transfer kinetics and increases the charge-transfer resistance (R ct ). Numerical values of R ct were extracted from a simulation of electrochemical impedance spectroscopy (EIS) spectra with the corresponding equivalent circuit. Cathodic polarization was employed prior to EIS measurements to effectively eliminate the metal ion interference. The results yielded a detection limit of 0.024 ng/L for diethyl phthalate (DEP) with a linear range from 2.22 ng to 1.11 µg. These results indicate a possibility of developing a household sensor for phthalate determination in Chinese liquor.

Enrichment-Free Rapid Detection of Phthalates in Chinese Liquor with Electrochemical Impedance Spectroscopy