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Exploring how urban form affects the Particulate Matter 2.5 (PM2.5) concentration could help to find environmentally friendly urbanization. According to the definition of geography, this paper constructs a comprehensive urban form evaluation index system applicable to many aspects. Four urban form metrics, as well as road density and five control variables are selected. Based on 2015 data on China’s 340 prefecture-level cities, the spatial regression model and geographically weighted regression model were used to explore the relationship between the urban form evaluation index system and PM2.5 pollution. The main results show that the spatial distribution of PM2.5 in China follows an increasing trend from northwest to southeast. Urban form indicators such as AI, LPI, PLAND, LSI and road density were all significantly related to PM2.5 concentrations. More compact urban construction, lower fragmentation of urban land, and lower density of the road network are conducive factors for improving air quality conditions. In addition, affected by seasonal changes, the correlation between urban form and PM2.5 concentration in spring and winter is higher than that in summer and winter. This study confirmed that a reasonable urban planning strategies are very important for improving air quality.

The Effect of Urban Form on PM2.5 Concentration: Evidence from China’s 340 Prefecture-Level Cities