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Hyperspectral imaging has recently emerged in the geosciences as a technology that provides rapid, accurate, and high-resolution information from lake sediment cores. Here we introduce a new methodology to infer particle size distribution, an insightful proxy that tracks past changes in aquatic ecosystems and their catchments, from laboratory hyperspectral images of lake sediment cores. The proposed methodology includes data preparation, spectral preprocessing and transformation, variable selection, and model fitting. We evaluated random forest regression and other commonly used statistical methods to find the best model for particle size determination. We tested the performance of combinations of spectral transformation techniques, including absorbance, continuum removal, and first and second derivatives of the reflectance and absorbance, along with different regression models including partial least squares, multiple linear regression, principal component regression, and support vector regression, and evaluated the resulting root mean square error (RMSE), R-squared, and mean relative error (MRE). Our results show that a random forest regression model built on spectra absorbance significantly outperforms all other models. The new workflow demonstrated herein represents a much-improved method for generating inferences from hyperspectral imagery, which opens many new opportunities for advancing the study of sediment archives.

Remote Sensing of Lake Sediment Core Particle Size Using Hyperspectral Image Analysis