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The efficiency of a thermochemical energy storage system can be improved by optimizing the structure of the thermochemical energy storage reactor. We proposed two modified structures for indirect heat transfer thermochemical energy storage reactors for a Ca(OH)2/CaO system to improve their heat transfer performance. Our results showed that improving convective heat transfer offered varying effects on heat transfer performance in different reaction processes. For a half-plate pin fin sinks (HPPFHS) reactor and a plate pin fin sinks (PPFHS) reactor, enhancing the convective heat transfer process could improve the heat transfer performance in the dehydration process for a porosity of 0.5, and the time needed to complete reaction was reduced by around 33% compared with plate fin sinks (PFHS) reactor. As for the hydration process, because heat conduction along the bed dominated heat transfer performance, this method had little effect. Furthermore, we found that enhancing heat conduction along the bed and convective heat transfer had different effects on reaction process at different reaction areas. The HPPFHS reactor had a lower pressure drop along the HTF channel and exorbitant velocity of heat transfer fluid (HTF) was unnecessary. Under the condition of the bed porosity of 0.8, due to the lower thermal conductivity of material, both modified reactor structures had little effect on dehydration. However, because the temperature difference between bed and HFT was bigger, the PPFHS reactor could reduce the time of completing the hydration reaction by 20%. Above all, when planning to modify the reactor structure to improve the heat transfer performance to enhance the reaction process, the heat conditions along the bed, convective heat transfer between HTF and the bed and material parameters should be considered totally.

Heat Transfer Enhancement of Indirect Heat Transfer Reactors for Ca(OH)2/CaO Thermochemical Energy Storage System