English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

Experimental and simulation studies for carbon dioxide (CO2) adsorption on porous silica glass were performed to reveal how surface heterogeneity can affect the adsorption mechanism of CO2. In performing the simulation, the structure of porous silica glass was modeled as a slit pore consisting of parallel walls of connected SiO4 units. The adsorption isotherms of CO2 at 283 K were generated for a series of pore widths using a Monte Carlo ensemble. The defective surfaces created by random removal of surface atoms and the surfaces containing hydroxyl functional groups were chosen to represent the surface heterogeneity for the simulation tasks. The isotherms derived for the defective surfaces showed a rapid adsorption at low pressures because of the stronger interaction between the rough nonuniform surfaces and CO2 molecules. For the role of surface functional groups, the adsorption isotherms dramatically increased with an increasing number of functional groups. The amount of CO2 adsorbed for randomly placed functional groups was greater than that for the presence of functional groups at the pore edges. The proper control of surface heterogeneity by manipulating both the amounts of hydroxyl surface groups and surface defects should help enhance the efficient capture of CO2 in porous silica glass.

Carbon Dioxide Capture in Homogeneous and Heterogeneous Surfaces of Porous Silica Glass