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This paper presents the results of an experimental study on the extraction of KCl and the improvement of the zinc grade of secondary dust obtained from rotary-hearth-furnace secondary dust (RHF secondary dust) using alkali leaching (Na2CO3 solution) and evaporation–crystallization processes. The effects of the liquid–solid ratio and Na2CO3 content on the element leaching ratio in the alkali leaching process, as well as the effects of the volume–evaporation ratio and cooling temperature on KCl extraction in the evaporation–crystallization process, were investigated. The results showed that the optimum liquid–solid ratio was 6:1, and the optimum quantity of Na2CO3 was 1.5 times the basic quantity. The recovery ratio of zinc reached 95.23%, and the leaching ratio of K reached 79.01%. The experimental results of the evaporation–crystallization process demonstrated that the evaporation temperature was 80 °C, the volume evaporation ratio was 50%, the cooling temperature was 25 °C, and the mass fraction of K2O in the obtained crystals was 58.99%.

Treatment of Secondary Dust Produced in Rotary Hearth Furnace through Alkali Leaching and Evaporation–Crystallization Processes