English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Two ethylene-octene copolymers (EOC) with the same melt flow index (MFI = 3 g/10 min) but different octene contents, being 20 and 35 wt % (EOC-20 and EOC-35), were compared with regard to sensitivity to electron beam crosslinking. Dynamic mechanical analysis (DMA) revealed a large influence of the octene content on the storage modulus and the glass transition temperature (Tg) but a smaller influence of irradiation on the properties below melting point (Tm). Rheology at 150 °C pointed out large differences in samples crosslinked in the 0–60 kGy range and at lower frequencies (0.1–1 Hz). The loss factor tanδ confirmed that before irradiation the two copolymers were very similar, while after irradiation to 120 kGy, the EOC-35 had considerably lower tanδ than EOC-20, which corresponds to a better elasticity (or a higher level of crosslinking). A high-temperature creep test showed a considerably lower creep for EOC with a higher octene content. An analysis of the insoluble gel content exhibited higher values for EOC-35 confirming a higher level of crosslinking. Analysis according to the Charlesby-Pinner equation revealed increased crosslinking-to-scission ratio, G(X)/G(S), for EOC-35. While the G(X) value changed only slightly, a significant decrease in the G(S) value was discovered

Influence of Branching Density in Ethylene-Octene Copolymers on Electron Beam Crosslinkability