English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

In order to further understand the shape memory mechanism of a silicon dioxide/shape memory polyurethane (SiO 2 /SMPU) composite, the thermodynamic properties and shape memory behaviors of prepared SiO 2 /SMPU were characterized. Dynamic changes in the molecular orientation and interphase structures of SiO 2 /SMPU during a shape memory cycle were then discussed according to the small angle X-ray scattering theory, Guinier's law, Porod approximation, and fractal dimension theorem. In this paper, a dynamic mechanical analyzer (DMA) helped to determine the glass transition start temperature ( T  g ) by taking the onset point of the sigmoidal change in the storage modulus, while transition temperature ( T  trans ) was defined by the peak of tan δ, then the test and the calculated results indicated that the T  g of SiO 2 /SMPU was 50.4 °C, and the T  trans of SiO 2 /SMPU was 72.18 °C. SiO 2 /SMPU showed good shape memory performance. The programmed SiO 2 /SMPU showed quite obvious microphase separation and molecular orientation. Large-size sheets and long-period structures were formed in the programmed SiO 2 /SMPU, which increases the electron density difference. Furthermore, some hard segments had been rearranged, and their gyration radii decreased. In addition, several defects formed at the interfaces of SiO 2 /SMPU, which caused the generation of space charges, thus leading to local electron density fluctuations. The blurred interphase structure and the intermediate layer formed in the programmed SiO 2 /SMPU and there was evident crystal damage and chemical bond breakage in the recovered SiO 2 /SMPU. Finally, the original and recovered SiO 2 /SMPU samples belong to the surface fractal system, but the programmed sample belongs to the mass fractal and reforms two-phase structures. This study provides an insight into the shape memory mechanism of the SiO 2 /SMPU composite.

polymers

The Difference in Molecular Orientation and Interphase Structure of SiO2/Shape Memory Polyurethane in Original, Programmed and Recovered States during Shape Memory Process