English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

1 H NMR methods in combination with dynamic light scattering were applied to study temperature behavior of poly(2-isopropyl-2-oxazoline) (PIPOx) homopolymer as well as PIPOx- b -poly(2-methyl-2-oxazoline) (PMeOx) and poly(2-ethyl-2-oxazoline) (PEtOx)- b -PMeOx diblock copolymers in aqueous solutions. 1 H NMR spectra showed a different way of phase transition for the main and side chains in PIPOx-based solutions. Additionally, the phase transition is irreversible for PIPOx homopolymer and partially reversible for PIPOx- b -PMeOx copolymer. As revealed by NMR, the phase transition in PEtOx-based copolymers solutions exists despite the absence of solution turbidity. It is very broad, virtually independent of the copolymer composition and reversible with some hysteresis. Two types of water molecules were detected in solutions of the diblock copolymers above the phase transition-"free" with long and "bound" with short spin-spin relaxation times T  2 . NOESY spectra revealed information about conformational changes observed already in the pre-transition region of PIPOx- b -PMeOx copolymer solution.

polymers

Temperature Behavior of Aqueous Solutions of Poly(2-Oxazoline) Homopolymer and Block Copolymers Investigated by NMR Spectroscopy and Dynamic Light Scattering