English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Poly(dimethylosiloxane) (PDMS) cross-linked by metal-ligand coordination has a potential functionality for electronic devices applications. In this work, the molecular dynamics of bipyridine (bpy)-PDMS-MeCl 2 (Me: Mn 2+ , Fe 2+ , Ni 2+ , and Zn 2+ ) are investigated by means of broadband dielectric spectroscopy and supported by differential scanning calorimetry and density functional theory calculations. The study of molecular motions covered a broad range of temperatures and frequencies and was performed for the first time for metal-ligand cross-linked PDMS. It was found that the incorporation of bpy moieties into PDMS chain prevents its crystallization. The dielectric permittivity of studied organometallic systems was elevated and almost two times higher ( ε ' ~4 at 1 MHz) than in neat PDMS. BpyPDMS-MeCl 2 complexes exhibit slightly higher glass transition temperature and fragility as compared to a neat PDMS. Two segmental type relaxations ( α and α ac  ) were observed in dielectric studies, and their origin was discussed in relation to the molecular structure of investigated complexes. The α ac  relaxation was observed for the first time in amorphous metal-ligand complexes. It originates from the lower mobility of PDMS polymer chains, which are immobilized by metal-ligand coordination centers via bipyridine moieties.

Effect of Metal-Ligand Coordination Complexes on Molecular Dynamics and Structure of Cross-Linked Poly(dimethylosiloxane)