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The dynamics of n-propanol confined in regular MCM-41  matrix with the pore size D  pore = 40 Å, under various matrix conditioning and sample confining conditions, using broadband dielectric spectroscopy (BDS), is reported. First, various drying procedures with the capacitor filling under air or N 2  influence the BDS spectra of the empty MCM-41 and the confined n-PrOH/MCM-41 systems , but have a little effect on the maximum relaxation time of the main process. Finally, various filling factors of n-PrOH  medium in the optimally treated MCM-41  system lead to unimodal or bimodal spectra interpreted in terms of the two distinct dynamic phases in the confined states.

Dynamics of Confined Short-Chain alkanol in MCM-41 by Dielectric Spectroscopy: Effects of matrix and system Treatments and Filling Factor