English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The synthesis and characterization of 4'-(4-methoxyphenyl)-3,2':6',3″-terpyridine ( 2 ) (IUPAC PIN 2 4 -(4-methoxyphenyl)-1 2 ,2 2 :2 6 ,3 2 -terpyridine) are described, and its coordination behaviour with cobalt(II) thiocyanate has been investigated. In a series of experiments, crystals were grown at room temperature by layering a MeOH solution of Co(NCS) 2 over a CHCl 3 solution of 2 using 1:1, 1:2 or 2:1 molar ratios of metal salt-to-ligand. Crystals harvested within 2-3 weeks proved to be the 1D-coordination polymer [Co( 2 )(NCS) 2 (MeOH) 2 ]  n  and powder X-ray diffraction (PXRD) confirmed that the crystals selected for single-crystal X-ray diffraction were representative of the bulk samples. Longer crystallization times with a Co(NCS) 2 to 2 molar ratio of 1:1 yielded crystals of [Co( 2 )(NCS) 2 (MeOH) 2 ]  n  (1D-chain) and the pseudopolymorphs [{Co( 2 ) 2 (NCS) 2 }·3MeOH]  n  and [{Co( 2 ) 2 (NCS) 2 }·2.2CHCl 3 ]  n  ((4,4)-nets), each type of crystal originating from a different zone in the crystallization tube. PXRD for this last experiment confirmed that the dominant product in the bulk sample was the 1D-coordination polymer.

Competition in Coordination Assemblies: 1D-Coordination Polymer or 2D-Nets Based on Co(NCS)2 and 4′-(4-methoxyphenyl)-3,2′:6′,3″-terpyridine