English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The development of Ir-based catalyst with high efficiency for oxygen evolution reaction (OER) in acidic conditions is of great significance to the development of clean energy, but it still remains a significant challenge for shape controlled synthesis of Ir-based catalysts. This article presented a facile one-pot synthesis method that is based on polyol method for preparing IrCu microspheres. In the process of synthesis, formaldehyde solution and ethylene glycol were used as reducing agent and solvent, respectively, while poly(vinylpyrrolidone) was used as surfactant and dispersant, and all of them played important roles in the successful synthesis of Ir-Cu microspheres. The Ir-Cu microspheres, as synthesized, showed well sphere shape and smooth surface, while their alloy features were quite clear and the composition could be adjusted. Benefitting from the synergistic electronic effect between the Iridium and Cupric atoms from the alloy, the IrCu 0.77 microspheres exhibited excellent electrocatalytic activity towards OER in 0.1 M HClO 4 electrolyte, and to achieve 10 mA cm -2 , IrCu 0.77 microspheres only required the overpotential of 282 mV, which was much lower than that of commercial Ir/C catalysts.

Facile Synthesis of IrCu Microspheres Based on Polyol Method and Study on Their Electro-Catalytic Performances to Oxygen Evolution Reaction