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In this study, ternary Cu₂SnS₃ (CTS) nanostructure materials with high crystallinity were successfully prepared via a facile solvothermal method, which was followed by high-temperature treatment. The morphology of the as-synthesized samples is uniform flower-like spheres, with these spheres consisting of hierarchical nanosheets and possessing network features. Sodium storage measurements demonstrate that the annealed CTS electrodes have high initial reversible capacity (447.7 mAh&amp;middot;g &amp;minus;1 at a current density of 100 mA&amp;middot;g &amp;minus;1 ), good capacity retention (200.6 mAh&amp;middot;g &amp;minus;1 after 50 cycles at a current density of 100 mA&amp;middot;g &amp;minus;1 ) and considerable rate capability because of their high crystallinity and unique morphology. Such good performances indicate that the high crystallinity CTS is a promising anode material for sodium ion batteries.

Flower-like Cu2SnS3 Nanostructure Materials with High Crystallinity for Sodium Storage