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Trace amounts of Co 3 O 4 modified TiO 2 nanorod arrays were successfully fabricated through the photochemical deposition method without adding any nocuous reagents. The Co 3 O 4 /TiO 2 nanorod arrays fabricated in acid solution had the highest photo-electrochemical activity. We elaborated on the mechanism of Co 3 O 4 -TiO 2 fabricated in different pH value solutions. The Co 3 O 4 -TiO 2 had a more remarkable photo-electrochemical performance than the pure TiO 2 nanorod arrays owing to the heterojunction between Co 3 O 4 and TiO 2 . The degradation of methylene blue and hydroquinone was selected as the model reactions to evaluate the photo-electrochemical performance of Co 3 O 4 -TiO 2 nanorod arrays. The Co 3 O 4 /TiO 2 nanorod arrays had great potential in waste water treatment.

Trace Amounts of Co3O4 Nano-Particles Modified TiO2 Nanorod Arrays for Boosted Photoelectrocatalytic Removal of Organic Pollutants in Water