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A series of neutral mononuclear lanthanide complexes  [Ln(HL) 2 (NO 3 ) 3 ]  (Ln = La, Ce, Nd, Eu, Gd, Dy, Ho) with rigid bidentate ligand, HL (4′-(1 H -imidazol-1-yl)biphenyl-4-carboxylic acid) were synthesized under solvothermal conditions. The coordination compounds have been characterized by infrared spectroscopy, thermogravimetry, powder X-ray diffraction and elemental analysis. According to X-ray diffraction, all the complexes are a series of isostructural compounds crystallized in the  P2/n  monoclinic space group. Additionally, solid-state luminescence measurements of all complexes show that  [Eu(HL) 2 (NO 3 ) 3 ]  complex displays the characteristic emission peaks of Eu(III) ion at 593, 597, 615, and 651 nm.

Novel Lanthanide (III) Complexes Derived from an Imidazole–Biphenyl–Carboxylate Ligand: Synthesis, Structure and Luminescence Properties