English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

A highly water and thermally stable metal-organic framework (MOF) Zn 2 (Pydc)(Ata) 2 ( 1 , H 2 Pydc = 3,5-pyridinedicarboxylic acid; HAta = 3-amino-1,2,4-triazole) was synthesized on a large scale using inexpensive commercially available ligands for efficient separation of C 2 H 2 from CH 4 and CO 2 . Compound 1 could take up 47.2 mL/g of C 2 H 2 under ambient conditions but only 33.0 mL/g of CO 2 and 19.1 mL/g of CH 4 . The calculated ideal absorbed solution theory (IAST) selectivities for equimolar C 2 H 2 /CO 2 and C 2 H 2 /CH 4 were 5.1 and 21.5, respectively, comparable to those many popular MOFs. The Q st values for C 2 H 2 , CO 2 , and CH 4 at a near-zero loading in 1 were 43.1, 32.1, and 22.5 kJ mol -1 , respectively. The practical separation performance for C 2 H 2 /CO 2 mixtures was further confirmed by column breakthrough experiments.

Gram-Scale Synthesis of an Ultrastable Microporous Metal-Organic Framework for Efficient Adsorptive Separation of C2H2/CO2 and C2H2/CH4