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Two new lanthanide-based coordination polymers, [Sm 2 (bzz)(ben) 6 (H 2 O) 3 ]·0.5H 2 O ( 1 ) and [Eu(bbz)(ben) 3 ] ( 2 ), were synthesized and characterized. The described products were formed from in situ-generated benzoate (ben) and N '-benzoylbenzohydrazide (bbz) ligands, which were the products of transformation of originally added benzhydrazide (bzz) under hydrothermal conditions. Compound 1 exhibits a one-dimensional (1D) double-chain structure built up from the connection of the central Sm 3+ ions with a mixture of bzz and ben ligands. On the other hand, 2 features a 3D network with a 4-connected (6 6 ) dia topology constructed from dinuclear [Eu 2 (ben) 6 ] secondary building units and bbz linkers. High-pressure CO 2 sorption studies of activated 1 show that maximum uptake increases to exceptionally high values of 376.7 cm 3 g -1 (42.5 wt%) under a pressure of 50 bar at 298 K with good recyclability. Meanwhile, 2 shows a typical red emission in the solid state at room temperature with the decay lifetime of 1.2 ms.

molecules/molecules online/molecules annual

Self-Assembly of 1D Double-Chain and 3D Diamondoid Networks of Lanthanide Coordination Polymers through In Situ-Generated Ligands: High-Pressure CO2 Adsorption and Photoluminescence Properties