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A new terthiophene-based imidazole luminophore 5,5'-(1 H -thieno[3,4-d]imidazole-4,6-diyl)bis(thiophene-2-carboxylic acid) (TIBTCH 2 , 5 ) was synthesized in one step from previously reported 4,6-di(thiophen-2-yl)-1 H -thieno[3,4-d]imidazole (DTTI, 4 ), and their photophysical properties were studied and compared accordingly. Under solvothermal conditions, reacting 5 with Mn(OAc) 2 yielded a new three-dimensional metal-organic framework (MOF, 6 ) which was structurally defined by single-crystal X-ray diffraction. In 6 , all Mn(II) ions octahedrally bind to carboxylate- O atoms to form a linear Mn 3 secondary building unit (SBU) that contains three distinct coordination modes. Importantly, 6 exhibits dual functional properties of ligand-based emission and metal-based magnetic behaviors.

Magnetism and Luminescence of a MOF with Linear Mn3 Nodes Derived from an Emissive Terthiophene-Based Imidazole Linker