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Herein, a highly N-rich covalent triazine framework (CTF) is applied as support for a Ru III complex. The bipyridine sites within the CTF provide excellent anchoring points for the [Ru(acac) 2 (CH 3 CN) 2 ]PF 6 complex. The obtained robust Ru III @bipy-CTF material was applied for the selective tandem aerobic oxidation-Knoevenagel condensation reaction. The presented system shows a high catalytic performance (&gt;80% conversion of alcohols to α, β-unsaturated nitriles) without the use of expensive noble metals. The bipy-CTF not only acts as the catalyst support but also provides the active sites for both aerobic oxidation and Knoevenagel condensation reactions. This work highlights a new perspective for the development of highly efficient and robust heterogeneous catalysts applying CTFs for cascade catalysis.

A Ru-Complex Tethered to a N-Rich Covalent Triazine Framework for Tandem Aerobic Oxidation-Knoevenagel Condensation Reactions