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A new tetradentate mixed aza-thioether macrocyclic ligand 2,6-dithia[7](2,9)-1,10-phenanthrolinophane ([13]ane(phenN 2 )S 2 ) was successfully synthesized. Reacting metal precursors [Fe(CH 3 CN) 2 (OTf) 2 ], Ni(ClO 4 ) 2 ·6H 2 O, and Cu(ClO 4 ) 2 ·6H 2 O with one equivalent of [13]ane(phenN 2 )S 2 afforded [Fe([13]ane(phenN 2 )S 2 )(OTf) 2 ] ( 1 ), [Ni([13]ane(phenN 2 )S 2 )](ClO 4 ) 2 ( 2 (ClO 4 ) 2 ), and [Cu([13]ane(phenN 2 )S 2 )(OH 2 )](ClO 4 ) 2 ( 3 (ClO 4 ) 2 ), respectively. The structures of [13]ane(phenN 2 )S 2 and all of its metal complexes were investigated by X-ray crystallography. The [13]ane(phenN 2 )S 2 was found to behave as a tetradentate ligand via its donor atoms N and S.

A New Tetradentate Mixed Aza-Thioether Macrocycle and Its Complexation Behavior towards Fe(II), Ni(II) and Cu(II) Ions