English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Thermal reactions of cobalt(II) salts with flexible N,N' -bis(pyrid-3-ylmethyl)adipoamide ( L ) and angular 4,4'-sulfonyldibenzoic acid (H 2 SDA) in H 2 O and CH 3 OH afforded a pair of supramolecular isomers: [Co 2 ( L )(SDA) 2 ], 1 , and [Co 2 ( L )(SDA) 2 ]⋅CH 3 OH⋅H 2 O, 2 . The structure of complex 1 can be simplified as a one-dimensional (1D) looped chain with L ligands penetrating into the middles of squares, forming a new type of self-catenated net with the (4 2 ⋅5 4 )(4) 2 (5) 2 topology, whereas complex 2 displays a 2-fold interpenetrated 2D net with the rare (4 2 ⋅6 8 ⋅8⋅10 4 )(4) 2 -2,6L1 topology. While both complexes 1 and 2 display antiferromagnetism with strong spin-orbital coupling, the antiferromagnetism of 2 is accompanied by a cross-over behavior and probably a spin canting phenomenon.

A Pair of CoII Supramolecular Isomers Based on Flexible Bis-Pyridyl-Bis-Amide and Angular Dicarboxylate Ligands