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New 3D conformers were synthesized to show a nanomolecular configuration with geometrically branched 2-diphenylaminofluorene (DPAF-C 2M ) chromophores using a symmetrical 1,3,5-triaminobenzene ring as the center core for the connection of three fused DPAF-C 2M moieties. The design led to a class of cis - cup -tris[(DPAF-C 2M )-C 60 (&gt;DPAF-C 9 )] 3D conformers with three bisadduct-analogous &lt;C 60 &gt; cages per nanomolecule facing at the same side of the geometrical molecular cis - cup -shape structure. A sequential synthetic route was described to afford this 3D configurated conformer in a high yield with various spectroscopic characterizations. In principle, a nanostructure with a non-coplanar 3D configuration in design should minimize the direct contact or π -stacking of fluorene rings with each other during molecular packing to the formation of fullerosome array. It may also prevent the self-quenching effect of its photoexcited states in solids. Photophysical properties of this cis - cup -conformer were also investigated.

Synthesis and Intramolecular Energy- and Electron-Transfer of 3D-Conformeric Tris(fluorenyl-[60]fullerenylfluorene) Derivatives