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Halogenido and carboxylato Ru(II) half-sandwich complexes of the general composition [Ru(η⁶- p -cym)(dpa)X]PF₆ ( 1 - 5 ) were prepared and thoroughly characterized with various techniques (e.g., mass spectrometry, NMR spectroscopy and X-ray analysis); dpa = 2,2'-dipyridylamine; p -cym = p -cymene; X = Cl - (for 1 ), Br - (for 2 ), I - (for 3 ), valproate(1-) (for 4 ) or 4-phenylbutyrate(1-) (for 5 ). A single-crystal X-ray analysis showed a pseudo-octahedral piano-stool geometry of [Ru(η⁶- p -cym)(dpa)I]PF₆ ( 3 ), with a η⁶-coordinated p -cymene, bidentate N -donor dpa ligand and iodido ligand coordinated to the Ru(II) atom. The results of the ¹H-NMR solution behaviour studies proved that the complexes 1 - 5 hydrolyse were in the mixture of solvents used (10% MeOD- d ₄/90% D₂O). Complexes 1 - 5 were in vitro inactive against the A2780 human ovarian carcinoma cell line, up to the highest tested concentration (IC 50 &gt; 100 μM).

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Half-Sandwich Ru(II) Halogenido, Valproato and 4-Phenylbutyrato Complexes Containing 2,2′-Dipyridylamine: Synthesis, Characterization, Solution Chemistry and In Vitro Cytotoxicity