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A series of new 8-arylhydrazono-2-(benzylsulfanyl)-7 H -purin-6-ones  6  were synthesized, their electronic absorption spectra in different organic solvents of varying polarities were investigated and their acid dissociation constants in both the ground and excited states were determined spectrophotometrically. The tautomeric structures of such products were elucidated by spectral analyses and correlation of their acid dissociation constants with the Hammett equation. The results indicated that the studied compounds  6  exist predominantly in the hydrazone tautomeric form  6A  in both the ground and excited states.

molecules/molecules online/molecules annual

Synthesis, Acidity Constants and Tautomeric Structure of the Diazonium Coupling Products of 2-(Benzylsulfanyl)-7H-purin-6-one in Its Ground and Excited States