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Microorganism-derived polyene polyketides have been shown to display a variety of biological activities and have attracted great interest due to their structurally intriguing chemical diversity. Two new polyenes were isolated from a culture broth of  Streptomyces  sp. KMC-002 obtained from a soil sample in an abandoned mine. The structures of these compounds were determined to be  α -pyrone-containing polyene analogues through analyses of HRFABMS, UV and NMR data, and were named Gombapyrones E ( 1 ) and F ( 2 ). Gombapyrone E ( 1 ) showed antibacterial activity against  Micrococcus luteus ,  Enterococcus hirae ,  Staphylococcus aureus  and MRSA.

Gombapyrones E and F, New α-Pyrone Polyenes Produced by Streptomyces sp. KMC-002