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The effect of electrochemically active MnO 2  as a coating material on the electrochemical properties of a Li 1.2 Mn 0.54 Ni 0.13 Co 0.13 O 2  (LTMO) cathode material is explored in this article. The structural analysis indicated that the layered structure of the LTMO was unchanged after the modification with MnO 2 . The morphology inspection demonstrated that the rod-like LTMO particles were encapsulated by a compact coating layer. The MnO 2  layer was able to hinder the electrolyte solution from corroding the LTMO particles and optimized the formation of a solid electrolyte interface (SEI). Meanwhile, lithium ions were reversibly inserted into and extracted from MnO 2 , which afforded an additional capacity. Compared with the bare LTMO, the MnO 2 -coated sample exhibited enhanced electrochemical performance. After the MnO 2  coating, the first discharge capacity rose from 224.2 to 239.1 mAh/g, and the initial irreversible capacity loss declined from 78.2 to 46.0 mAh/g. Meanwhile, the cyclic retention climbed up to 88.2% after 100 cycles at 0.5 C, which was more competitive than that of the bare LTMO with a value of 71.1%. When discharging at a high current density of 2 C, the capacity increased from 100.5 to 136.9 mAh/g after the modification. These investigations may be conducive to the practical application of LTMO in prospective automotive Li-ion batteries.

Exploring the Effect of a MnO2 Coating on the Electrochemical Performance of a Li1.2Mn0.54Ni0.13Co0.13O2 Cathode Material