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We show that the kinetics of endothermal and exothermal effects occurring in the supercooled liquid state and upon crystallization of metallic glasses can be well reproduced using temperature dependences of their shear moduli. It is argued that the interrelation between the heat effects and shear modulus relaxation reflects thermally activated evolution of interstitial-type defect system inherited from the maternal melt.

metals

Heat Effects Occurring in the Supercooled Liquid State and Upon Crystallization of Metallic Glasses as a Result of Thermally Activated Evolution of Their Defect Systems